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Elementary Electrochemistry

By Prof. Angshuman Roy Choudhury   |   IISER Mohali
Learners enrolled: 150
ABOUT THE COURSE:
This course would highlight the basic concepts of electrochemistry in the elementary level and will be combined with some basic experiments to understand the theories. Construction of electrochemical cells, fuel cells and their applications, laws of electrolysis, theory of conduction of electricity in solution, ionic equilibrium etc will be discussed in detail. Practical applications like cyclic voltammetry and polarography will be introduced

INTENDED AUDIENCE: B.Sc Chemistry Students

PREREQUISITES: Knowledge of thermodynamics

INDUSTRY SUPPORT: Chemical industry
Summary
Course Status : Upcoming
Course Type : Core
Duration : 8 weeks
Start Date : 20 Feb 2023
End Date : 14 Apr 2023
Exam Date : 29 Apr 2023 IST
Enrollment Ends : 20 Feb 2023
Category :
  • Chemistry
Credit Points : 2
Level : Undergraduate/Postgraduate

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Course layout

Week 1: (i) Introduction to the course and evaluation components : Introduction to Electrochemistry
           (ii) Electrochemistry: The laws of electrochemistry and electrolysis : Faraday’s laws of Electrolysis, Arrhenius theory of electrolytic dissociation, concept of units in electrochemistry.
      (iii) Electrochemistry: Electrochemical cells : Electrochemical potential, the Nernst equation, electrochemical cell, standard electrode potential and cell potential, reaction Gibbs energy and cell potential.
Week 2: (i) Electrochemical Cells : Cell EMF and equilibrium constant, activity coefficient, construction of an electrochemical cell and calculation of cell EMF and electrochemical series Various electrodes (Glass, SHE, Calomel etc) and their applications, Liquid junction potential, concentration cell, polarization and overpotential
             (ii) Applications of EMF measurement : Demonstration Experiments of EMF measurement
Week 3: Fuel cell : Construction and Application
Week 4: Electrolytic solutions : Migration of ions, the transport number, Hittorf’s rule and determination of transport number. Conductance in solution, specific conductance, equivalent conductance, determination of conductance, equivalent conductance at infinite dilution.
Week 5: (i) Kohlrausch’s Law and ionic mobilities : Kohlrausch’s Law, its applications, ionic mobilities, weak electrolytes, degree of dissociation, hydration of ions.
               (ii)Conductometric titrations : Theory and experiments on Conductometric titrations.
Week 6: Debye-Hückel Theory : Theory and applications of Debye- Hückel limiting law
Week 7: Ionic equilibrium : Solubility product and activity product, solubility product from EMF, dissociation constant of weak electrolyte, ionic product, pH and pOH, salt hydrolysis and buffer solutions.
Week 8: Cyclic voltammetry and Polarography : Theory and applications.

Books and references

1.Thomas Engel and Philip Reid, Physical Chemistry, Pearson Publication 2006.
2.‘The Elements of Physical Chemistry’, P.W. Atkins & Julio de Paula, 8th edition, Oxford University Press, Oxford 2006.
3.P. C. Rakshit, Physical Chemistry, 7th Edition, Sarat Book Distributors, Kolkata, 2004.
4.S. Glasstone, An Introduction to Electrochemistry, Affiliated East West Press 1942.

Instructor bio

Prof. Angshuman Roy Choudhury

IISER Mohali
Prof. Angshuman Roy Choudhury. The instructor has obtained his Ph. D. in 2005 from Indian Institute of Science, Bangalore working in the area of small molecule X-ray crystallography. Following that he has worked in the University of Liverpool as a post-doctoral fellow from October, 2004 to September, 2007. Then he moved to BITS, Pilani as Assistant Professor in Chemistry. From there, he moved to IISER Mohali in December, 2009 as Assistant Professor in chemistry. He has more than 100 publications in various international journals, guided two PhD students and a few masters students at IISER Mohali. He offers the same course at IISER Mohali in the August Semester.

Course certificate

The course is free to enroll and learn from. But if you want a certificate, you have to register and write the proctored exam conducted by us in person at any of the designated exam centres.
The exam is optional for a fee of Rs 1000/- (Rupees one thousand only).
Date and Time of Exams: 29 April 2023 Morning session 9am to 12 noon; Afternoon Session 2pm to 5pm.
Registration url: Announcements will be made when the registration form is open for registrations.
The online registration form has to be filled and the certification exam fee needs to be paid. More details will be made available when the exam registration form is published. If there are any changes, it will be mentioned then.
Please check the form for more details on the cities where the exams will be held, the conditions you agree to when you fill the form etc.

CRITERIA TO GET A CERTIFICATE

Average assignment score = 25% of average of best 6 assignments out of the total 8 assignments given in the course.
Exam score = 75% of the proctored certification exam score out of 100

Final score = Average assignment score + Exam score

YOU WILL BE ELIGIBLE FOR A CERTIFICATE ONLY IF AVERAGE ASSIGNMENT SCORE >=10/25 AND EXAM SCORE >= 30/75. If one of the 2 criteria is not met, you will not get the certificate even if the Final score >= 40/100.

Certificate will have your name, photograph and the score in the final exam with the breakup.It will have the logos of NPTEL and IISER Mohali .It will be e-verifiable at nptel.ac.in/noc.

Only the e-certificate will be made available. Hard copies will not be dispatched.

Once again, thanks for your interest in our online courses and certification. Happy learning.

- NPTEL team


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